Kinetic Modeling of Phosphate Adsorption onto Algae-Saturated Chitosan Composites from Aqueous Solution under Batch Conditions
Sonal Kumari *
Department of Soil Science & Agricultural Chemistry, Institute of Agricultural Science, Banaras Hindu University, Varanasi-221005, India and Department of Soil Science & Agricultural Chemistry, Bihar Agricultural University, Sabour, Bhagalpur-821310, India.
Nirmal De *
Department of Soil Science & Agricultural Chemistry, Institute of Agricultural Science, Banaras Hindu University, Varanasi-221005, India.
*Author to whom correspondence should be addressed.
Abstract
Phosphate contamination in water bodies has emerged as a major environmental concern due to its role in eutrophication and water quality degradation. This study investigates the phosphate adsorption behaviour of algae-saturated chitosan composites synthesised using Spirulina platensis under batch experimental conditions. The adsorption performance was evaluated at an initial phosphate concentration of 50 mg L⁻¹, using 1.0 g L⁻¹ of the composite, at ambient temperature and pH 5.65 ± 0.1. The maximum phosphate removal efficiency reached 24.04 %, with adsorption equilibrium achieved within 120 minutes. Kinetic modelling indicated that the pseudo-second-order model (R² = 0.983) provided a better fit than the pseudo-first-order model (R² = 0.737), suggesting that chemisorption governs the adsorption process. The equilibrium adsorption capacity (qe) calculated from the pseudo-second-order model was 13.51 mg g⁻¹, closely matching the experimental value of 12.04 mg g⁻¹. These results demonstrate the synergistic potential of algal biomass and chitosan as a low-cost, biodegradable, and efficient biosorbent for phosphate removal from aqueous solutions. The study offers a promising approach for developing sustainable materials for water purification applications.
Keywords: Adsorption kinetics, algae-saturated chitosan composite, batch adsorption, biosorbent, phosphate removal spirulina platensis, pseudo-first-order model, pseudo-second-order model, wastewater treatment